Therefore, a formidable challenge for the universal application of SIBs and PIBs is to identify and synthesize practical SIB and PIB anode electrode materials with high energy density and long cycle stability. To date, few anode materials for SIBs and PIBs can match the status of commercial graphite in LIBs. Finally, we summarize the challenges of the development of Sb-based materials for Na/K-ion batteries and propose potential research directions for their further development. Moreover, corresponding examples are presented to illustrate the advantages or disadvantages of these anodes. This review systematically introduces the recent research progress of a variety of Sb-based anodes for SIBs and PIBs from the perspective of composition selection, preparation technologies, structural characteristics, and energy storage behaviors. To address such drawbacks, many strategies and a variety of Sb-based materials have been developed in recent years. However, Sb-based anodes have the drawbacks of large volume changes and weak charge transfer during the charge and discharge processes, thus leading to poor cycling and rapid capacity decay. Antimony (Sb) plays an important role in SIBs and PIBs because of its high theoretical capacity, proper working voltage, and low cost. The development of sodium-ion (SIBs) and potassium-ion batteries (PIBs) has increased rapidly because of the abundant resources and cost-effectiveness of Na and K.
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